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JEE Main Chemistry Class 12 Haloalkanes and Haloarenes Part 2 Questions
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Question : 8
Total: 22
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason
(
R
)
:
Assertion (A) :
S
N
2
reaction of
C
6
H
5
CH
2
Br
occurs more readily than the
S
N
2
reaction of
CH
3
CH
2
Br
.
Reason (R) : The partially bonded unhybridized p-orbital that develops in the trigonal bipyramidal transition state is stabilized by conjugation with the phenyl ring.
In the light of the above statements, choose the most appropriate answer from the options given below :
[9 Apr 2024 Shift 1]
(A) is not correct but (
R
) is correct
Both (A) and (R) are correct but (R) is not the correct explanation of (A)
Both (A) and (R) are correct and (R) is the correct explanation of (A)
(A) is correct but (R) is not correct
Validate
Solution:
The benzyl group acts in much the same way using the
π
-system of the benzene ring for conjugation with the p-orbital in the transition state.
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