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JEE Main Chemistry Class 11 Solutions Part 2 Questions
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© examsnet.com
Question : 2
Total: 80
2.5
g
of a non-volatile, non-electrolyte is dissolved in
100
g
of water at
25
∘
C
. The solution showed a boiling point elevation by
2
∘
C
. Assuming the solute concentration in negligible with respect to the solvent concentration, the vapour pressure of the resulting aqueous solution is ______
mm
of
Hg
(nearest integer)
[Given : Molal boiling point elevation constant of water
(
K
b
)
=
0.52
K
.
kg
mol
−
1
,
1
atm
pressure
=
760
mm
of
Hg
, molar mass of water
=
18
g
mol
−
1
]
[4 Apr 2024 Shift 1]
Your Answer:
Validate
Solution:
2
=
0.52
×
m
m
=
2
0.52
According to question, solution is much diluted
so
∆
P
P
∘
=
n
solute
n
solvent
∆
P
P
∘
=
m
1000
×
M
solvent
∆
P
=
P
∘
×
m
1000
×
M
solvent
=
760
×
2
1000
1000
×
18
=
52.615
P
5
=
760
−
52.615
=
707.385
mm
of
Hg
© examsnet.com
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