Concept:Electronegativity in Group 15 decreases down the group. The drop from N to P is large, but below P the values change very slowly.
Explanation:Pauling electronegativity values (approximate):
EN(N)=3.0,
EN(P)=2.1,
EN(As)=2.0,
EN(Sb)=1.9,
EN(Bi)=1.9.
The given condition is:
∣EN(X)−EN(P)∣>∣EN(P)−EN(Y)∣.
This means X must have electronegativity far from P, while Y must have electronegativity close to P.
Check each option:
Option A: X = As, Y = Bi. Differences:
∣2.0−2.1∣=0.1 and
∣2.1−1.9∣=0.2.
0.1>0.2? No.
Option B: X = Bi, Y = N. Differences:
∣1.9−2.1∣=0.2 and
∣2.1−3.0∣=0.9.
0.2>0.9? No.
Option C: X = N, Y = As. Differences:
∣3.0−2.1∣=0.9 and
∣2.1−2.0∣=0.1.
0.9>0.1? Yes. Correct.
Option D: X = As, Y = Sb. Differences:
∣2.0−2.1∣=0.1 and
∣2.1−1.9∣=0.2.
0.1>0.2? No.
Thus, X = N and Y = As.
Shortcut:For Group 15, the electronegativity drops sharply from N to P but then decreases very little. So X must be N (far from P) and Y must be an element just below P (As) with nearly equal electronegativity.
Answer:Option C: N & As