Let the weak electrolyte
AxBy dissociate in water as follows:
AxBy⇌xAy++yBx−Let the initial concentration of
AxBy be
c, and let the degree of dissociation be
α.
At equilibrium,
Concentration of undissociated
AxBy=c(1−α)Concentration of
Ay+=cxαConcentration of
Bx−=cyαK=[AxBy][Ay+1]x[Bx−]ySubstituting equilibrium concentrations:
K=c(1−α)(cxα)x(cyα)ySimplify:
K=cx+y−1xxyy1−ααx+ySince the solution is concentrated,
α is small, but generally in such problems the expression is kept exact. However, for simplification, at high concentration the term
(1−α)≈1 is often used if it is a weak electrolyte.
So approximately:
K≈cx+y−1xxyyαx+yαx+y=cx+y−1xxyyKα=(cx+y−1xxyyK)x+y1This matches Option B:
α=(cx+y−1xxyyK)x+y1