NCERT Class XI Chemistry Equilibrium Solutions

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Question : 4
Total: 73
Write the expression for the equilibrium constant, Kc for each of the following reactions :
(i) 2NOCl(g)2NO(g)+Cl2(g)
(ii) 2Cu(NO3)2(s)2CuO(s)+4NO2(g)+O2(g)
(iii) CH3COOC2H5(aq)+H2O(l)CH3COOH(aq)+C2H2OH(aq)
(iv) Fe(aq)3++3OH(aq)Fe(OH)3(s)
(v) I2(s)+5F2(g)2IFe5(g)
Solution:  
(i) Kc =
[NO(g)]2[Cl2(g)]
[NOCl(g)]2

(ii) Kc =
[CuO(s)]2[NO2(g)]4[O2(g)]
[Cu(NO3)2(g)]2
= [NO2(g)]4[O2(g)]
(iii) Kc =
[CH3COOH(aq)][C2H5OH(aq)]
[CH3COOC2H5(aq)][H2O(l)]
=
[CH3COOH(aq)][C2H5OH(aq)]
[CH3COOC2H5(aq)]

(iv) Kc =
[Fe(OH)3(s)]
[Fe(aq)3+][OH(aq)03
=
1
[Fe(aq)3+][OH(aq)]3

(v) Kc =
[IF5(g)]2
[I2(s)][F2(g)]5
=
[IF5(g)]2
[F2(g)]5

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